INTRODUCTION


1.1             History
The earliest on set of solar energy use to desalinate water is widely accredited to Aristotle during the fourth century B.C.E.Earlier attributions reference the Bible & Moses’ use of a piece of wood to remove the “bitterness” from water (Exodus 15:25, English Standard Version). The first documented account of solar distillation use for desalination was by Giovani Batista Della Porta in 1958.However, no solar distillation publication of any repute leaves out the Father of solar distillation, Carlos Wilson, the creator of the first modern sun-powered desalination plant, built in Las Salinas (The Salts), Chile in 1872.

This desalination plant, "can be considered to be the first industrial installation for exploitation of solar energy." The Las Salinas plant was envisioned to take advantage of the nearby saltpeter mining effluent to supply the miners and their families freshwater. The facility was quite large for its time and now.
        
The plant was constructed of wood and timber framework covered with one sheet of glass. It consisted of 64 bays having a total surface area of 4450 m2 and a total land surface area of 7896 m2. It produced 22.70 m3 of fresh water per day. The plant was in operation for about 40 years until the mines were exhausted."

The inner surface of the base known as basin liner is blackened to efficiently absorb the solar radiation incident on it. There is a provision to collect distillate output at lower ends of top cover. The brackish or saline water is fed inside the basin for purification using solar energy. The performance of a conventional solar distillation system can be predicted by various methods such as, computer simulation (Cooper, 1969), thermic circuit and the diagrams (Frick, 1970), periodic and transient analysis (Cooper, 1970; Nayak et al., 1980; Sodhaet al., 1980; Tiwari and BapeswarRao, 1983; El-Sayed,1983; Tiwari and Madhuri, 1987), iteration methods(Toure and Meukam, 1997), numerical methods (Lofetal., 1961; Sartori, 1987; Sharma and Mullick, 1991).

In most of the above-mentioned methods, the basic internal heat and mass transfer relations, given by Dunkle (1961), has been used.


1.2             Defination 
A device used for converting brackish water into potable water using solar energy is called solar still.

1.3             Why required solar still
      Water is one of the prime elements responsible for life on earth. It covers three-fourths of the surface of the earth. However, most of the earth’s water is found in oceans as salt water, contains too much of salt, cannot be used for drinking, growing crops or most industrial uses. The remaining earth’s water supply is fresh water. Most of this is locked up in glaciers and ice caps, mainly at the north and south poles. If the polar ice caps were to melt, the sea level would rise and would flood much of the present land surfaces in the world. The rest of the world’s supply of fresh water is found in water bodies such as rivers, streams, lakes, ponds and in the underground. So there is an important need for clean and pure drinking water. In many coastal areas where sea water is abundant but potable water is not available, solar water distillation is one of the many processes that can be used for purification as well as desalination. Solar still is the widely used solar desalination device.

1.4             How it's work

      The basin of the still is filled with brackish or sea water, the incident solar radiation is transmitted through the glass cover and is absorbed as heat by a black surface (basin) which contains the brackish water.Thus the water is heated and gives off water vapor. The vapor condenses on the glass cover, which is at a lower temperature because it is in contact with the ambient air.
      
      If the glass cover is tilted, the formed condensation drops will start running down the cover by gravitational forces, and may then be collected in a channel to go out the side of the still to a storage tank.

Fig 1: Solar Still
1.5             Natural and Distillation
    In this method brackish or salient water is evaporated using thermal energy and the resulting steam is collected and condensed as final product.
   Distillation process is considered to be one of the simplest and widely adopted techniques for      converting sea water in to fresh water. More than 90% of the worldwide installed sea water desalination capacity is based on distillation process. One of the main advantages of the distillation   process is that it required heat only up to120 C which can be supplied from solar energy or other cheap fuels, while in reverse osmosis, vapour compression, and electro dialysis processes, some          mechanical or electrical energy in used.
      Solar energy is abounded is, never lasting, available on site and population free energy. however the         cost of its collection and utilization become high because it is diffuses, of low intensity, and intermitted and therefore, required some kind thermal energy storage but for application like distillation of brackish water, the intermittent nature of solar energy will not limit its use and distilled water will be produced, as and when solar energy available. Because of the simplicity of apparatus design, requirement of fresh water, and free availability of thermal energy, work in the field of solar distillation is in progress for more than one hundred year.

1.6             Basic requirements of a good bottom reflector type solar still

·           Be easily assembled in the field.

·           Be constructed with locally available materials.

·           Be light weight for ease of handling and transportation.

·           Have an effective life of 10 to 20 Yrs.

·           No requirement of any external power sources.

·           Can also serve as a rainfall catchment surface.

·           Material with good reflectivity.

·           Materials used should not contaminate the distillate.

·           Meet standard civil and structural engineering standards, and,

·           Should be low in cost.


1.7             Materials for solar stills
Glazing: Should have high transmittance for solar radiation, opaque to thermal radiation, resistance to abrasion, long life, low cost, high wet ability for water, lightweight, easy to handle and apply, and universal availability. Materials used are: glass or treated plastic.

Liner: Should absorb more solar radiation, should be durable, should be water tight, easily cleanable, low cost, and should be able to withstand temperature around 100 Deg C. Materials used are: asphalt matt, black butyl rubber, black polyethylene etc.

Sealant: Should remain resilient at very low temperatures, low cost, durable and easily applicable. Materials used are: putty, tars, tapes silicon, and sealant.

Basin tray: Should have long life, high resistance to corrosion and low cost. Materials used are: wood, galvanized iron, steel, aluminum, asbestos cement, masonry bricks, concrete, etc.

Condensate channel: Materials used are: aluminum galvanized iron, concrete, plastic material, etc.

Reflector: Aluminum foil, Mirror, High grade PVC sun reflector fabric, Grey polyester, Customized Polycarbonate etc.


1.8             Components of external bottom reflector type solar still
·         Basin
·         Black Liner
·         Transparent Cover
·         Condensate Channel
·         Sealant
·         Reflector
·         Insulation
·         Supply and Delivery System

1.9 Solar still output depends on many parameters
A. Climatic Parameters
·         Solar Radiation
·         Ambient Temperature
·         Wind Speed
·         Outside Humidity
·         Sky Conditions

B. Design Parameters
·         Single Slope or double Slope
·         Glazing material
·         Water depth in basin
·         Bottom insulation
·         Orientation of still
·         Inclination of glazing
·         Spacing between water and glazing
·         Type of solar still

C. Operational Parameters
·         Water Depth
·         Preheating of water
·         Coloring of water
·         Salinity of water
·         Rate of alge growth
·         Input water supply arrangement (continuously or in batches)

  
1.10 Classification of Solar Distillation Systems

v  Passive solar still :
    The passive solar still systems are conventional solar still systems which use solar energy as the only source of thermal energy.Passive solar still operates in low temperature and the daily productivity is comparatively low.
v  Active solar still :
      The active solar stills, extra thermal energy is given to the passive solar still for faster evaporation.to         increase the evaporation rate in an active mode the extra thermal energy is fed into the basin. To increase the productivity of solar still, the various active methods are being carried out by many researchers. Most of the works were based on the flat plate collector and concentrating collector.

1.11 Method of Purification of Water
1.11.1 Basin type solar still
Such solar stills have been operated for farm and community use in several countries. It consists of a blackened basin containing saline water at a shallow depth, over which is a transparent air tight cover that encloses completely the space above the basin. It has a roof-like shape. The cover  which is usually glass, may be of plastic is sloped towards a collection trough. Solar radiation passes  through the cover and is absorbed and converted into heat in the black surface. Impure water in the basin or tray is heated and the vapor produced is condensed to purified water on the cooler interior of the roof. The transparent roof material, (mainly glass) transmits nearly all radiation falling on it and absorbs very little; hence it remains cool enough to condense the water vapor. The condensed water flows down the sloping roof and is collected in troughs at the bottom.

v Types of the basin type solar still systems
A. single-slope
B. double-basin solar still
C. single-slop triple-basin solar still
D. pyramid-shaped solar still
E. conventional solar still
F. single-basin solar still

1.12 Vertical solar stills with a flat plate solar collector :
The distillation unit consists of parallel vertical plates. The first plate is insulated on its front side and the last plate is exposed to ambient. Each plate in the enclosure is covered with wetted cloth on one side. The cloth is extended into a feed through along the upper edge of each plate. Feed water in the through is then drawn onto the plate surface by capillary. Excess water moves down the plate and is conducted out of the still. The last plate is cooled by air or water. The authors found that, the   distillation output increases slightly when the plate number is over 5, and it increased by about 34% and 15% when the evaporating plate numbers are 1 and 6, respectively.
1.13 Solar still integrated with mini solar pond :
Solar pond is an artificially constructed pond in which significant temperature rises are caused to occur in the lower regions by preventing convection. Solar ponds are used for collection and storage of solar energy and it is used for various thermal applications like green-house heating, process heat in dairy plants, power production and desalination. The results show that, average increase in productivity, when a pond is integrated with a still is 27.6% and when pond and sponge are integrated with a still is 57.8%. Industrial effluent was used as feed for fin type single basin solar still and stepped solar still. A mini solar pond connected to the stills to enhance the productivity and tested individually. The results show that, maximum productivity 100% was obtained when the fin solar still was integrated with pebble and sponge. The productivity increases with increase in solar intensity and water glass temperature difference and decreases with increase in wind velocity. Pebbles, baffle plates, fins and sponges are used in the stepped solar still for productivity augmentation. Their finding shows that, maximum productivity of 78% occurred when fins and sponges were used in the stepped solar still and also found that the productivity during night also improved when pebbles were used in the solar stills.
There are three main types of solar stills: the box solar still, the cone solar still and the pit solar still. 
A.    Box Solar Still


Fig 2: Box Solar Stills
The box shaped solar still is fairly complex compared to the other solar stills made for obtaining pure emergency drinking water. This type of still is usually created with a box that has a slanted glass or plastic top with an insulated bottom. A set of tubes allow in impure water and let out over flow and pure distilled water. Maintaining a tight seal on a box shaped solar still is essential. Clearly, this is more of a home project for a green minded person, but having a solid understanding of how all solar stills work might come in handy when trying to construct one from scratch for emergency drinking water.
B.     Cone Solar Still

Fig 3: Cone Solar Still
A cone shaped solar still is a method of treating impure emergency drinking water rather than gathering it from the atmosphere. A cone is constructed out of plastic designed so that impure water in the bottom evaporates and is captured in a makeshift reservoir as it runs down the side, relieved of impurities. The Water cone is commercial solar still that allows you to distill water naturally at home or on the go with having to construct a solar still of your own. Designed as a water purification system that can generate potable water out of even brackish sea water, the Water cone is also a candidate for providing clean drinking water in developing and failed nations.
C.    Pit Solar Still
Pit shaped solar stills are the simplest solar still to make and require little equipment or technical know-how. Simply dig a pit in the earth approximately two feet deep and place a Number 10 sized can at the bottom. If available, set a drinking tube in the bottom of the can leading out of the hole. Then secure a sheet of plastic over the hole a place a stone in the sheet so that it indents the sheet to just above the can's lid. So long as this solar still receives plenty of sun, it will provide a pint or more of emergency drinking water.
Fig 4: Pit Solar Still